Ring-Shaped Rhenium(I) Multinuclear Complexes: Improved Synthesis and Photoinduced Multielectron Accumulation
نویسندگان
چکیده
منابع مشابه
Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids.
Large porphyrinoids with three Rh(CO)2 groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C3v-isomer and the Cs-isomer depends on the solvent polarity.
متن کاملTransmittance of MIM Waveguides Containing Semi-Circular Ring Shaped and Rectangular Ring Shaped Grooves
In this paper the transmittance of metal-insulator-metal (MIM) waveguides containing semi-circular ring shaped and rectangular ring shaped grooves are investigated. By varying groove parameters their effects on the transmittance of the MIM waveguides are investigated. The results show that the transmittance spectra of the waveguides have maximum and minimum points, and by using appropriate para...
متن کاملMultinuclear Metal Nucleobase Complexes
Of all properties of metal nucleobase complexes, formation of multinuclear species appears to be an outstanding feature. After a brief introduction into well known polymeric metal nucleobase complexes, three aspects recently Studied in our laboratory will be dealt with in more detail: (i) Heteronuclear complexes derived from trans-[(amine)(2)Pt(1-MeC)(2)](2+) (1-MeC=1-methylcytosine). They form...
متن کاملSynthesis of novel photofunctional multinuclear complexes using a coupling reaction.
Various photofunctional metal complexes with functional groups, i.e. bromo and vinyl groups, were integrated into hetero-multinuclear complexes using the Mizoroki-Heck reaction. The obtained trinuclear complexes absorb a wide range of visible light and have a long excited state lifetime and the photocatalytic ability to obtain CO2 reduction.
متن کاملsynthesis and characterization of some new cyclometalated organoplatinum(ii) complexes containing phosphite ligand
در این تحقیق روشی جهت سنتز یک سری از کمپلکس های پلاتین (ii) حاوی لیگاند های دهنده ی فسفری شامل فسفیت و فسفین ارائه شده است. واکنش پیش ماده ی پلاتین (ii)،trans/cis- [ptcl2(sme2)2] ، با 2 اکی مولار از لیگاند p(oph)3در حلال بنزن کمپلکس1، cis-[ptcl2(p(oph)3)2] را تولید می نماید. جهت سنتز کمپلکس سایکلو متال فسفیتی، کمپلکس 1 با 1 اکی والان واکنشگر ptcl2 در حلال زایلن در شرایط رفلاکس زیر گاز آرگون م...
ذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2014
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic501196q